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31.
张洁辉  郑邦乾 《合成化学》1997,5(3):311-316
以二乙烯苯和双丙烯酸多缩乙二醇酯为交联剂、聚醋酸乙烯酯(PVAc)或它与醋酸丁酯(BAC)的混合物为致孔剂、BPO为引发剂,用悬浮聚合随后水解的方法制得了部分水解聚(丙烯酸甲酯-醋酸乙烯酯-甲基丙烯酸甲酯)[HP(MA-VAc-MMA)]多孔载体,研究了PVAc及(PVAc+BAC)用量、分子量及混合比对HP(MA-VAc-MMA)孔结构的影响。结果表明,当PVAc的M>2.5×105,PVAc/BAC为2.3,用量为10~20%时,可制得孔隙率较高,孔径分布较窄,孔表面积较大的多孔载体。这种载体适用于微生物固定化。  相似文献   
32.
Total cross section measurements for the 102Pd(p, γ)103Ag and 116Sn(p, γ)117Sb reactions have been performed in the proton energy range 2.6 to 4.25 MeV, and for the 112Sn(α, γ)116Te reaction over the alpha beam energy range 7.0 to 10.5 MeV. An activation technique was used in which gamma rays from decays of the reaction products were detected off-line by two hyper-pure germanium detectors in a low background environment. Where possible, reaction rates are derived and the results compared to those of calculations generated by the NON-SMOKER and the MOST statistical model codes so as to judge their applicability for describing the cross sections needed for network calculations of nucleosynthesis in explosive astrophysical environments via the γ- and rp-processes.  相似文献   
33.
One of the key differences of a semiconductor optical amplifier (SOA) with internal lasing oscillation (ILO) from a SOA with external light injection (ELI) lies in a carrier-sharing mechanism. Since the internal lasing mode shares the same pool of carriers with the signals, the carriers (or photons) withdrawn from the circulating laser mode speed up the gain recovery. On the other hand, the external light injected into the SOA shortens the carrier recovery time through optical pumping without any carrier sharing involved. To find out a better scheme, we have made a comparative investigation on the effects of the ILO and ELI on the SOA performance. It turns out by way of simulation that the ELI scheme provides faster gain recovery, shorter carrier lifetime, and higher saturation power when the external injection power is higher than the internal lasing power. The performance enhancement is not so pronounced with the carrier-sharing mechanism, as the internal lasing mode itself gives rise to severe longitudinal spatial hole burning (LSHB). Nevertheless, the ILO scheme is preferable for linear-amplification applications. We also examine the use of the ELI for low-crosstalk optical amplifiers. It is found that the ELI scheme does not bring in a very strong resonance peak in the crosstalk, which appears in a SOA with ILO due to relaxation oscillations of the lasing mode. In comparison to the ILO in SOAs, the ELI into SOAs is likely to leave more optical gain for multi-channel amplification without any sacrifice on the crosstalk.  相似文献   
34.
B+注入HgCdTe外延材料的红外透射光谱分析   总被引:6,自引:5,他引:1  
运用多层模型和膜系传递矩阵以及非线性二乘法,模拟了B+注入碲镉汞外延材料的红外透射光谱,结果表明B+注入碲镉汞外延材料的红外透射光谱能够很好地理论再现,并由此获得了结区的自由载流子浓度分布、迁移率、面自由载流子浓度以及折射率和消光系数等相关参量,所得结果与微分Hall法测试的结果是一致的.计算结果也表明B+注入HgCdTe导致红外透射率变化的根本原因是注入层的高载流子浓度的等离子效应改变了该层的折射率和消光系数.  相似文献   
35.
Given a target contained in a constrained set and an impulse control system governing the evolutions of runs or executions, that are hybrids of continuous and discrete evolutions, this paper studies and provides several characterizations of the capture basin of the target viable in the constrained set. It is the subset of initial runs from which start at least one run viable in the constrained set until it reaches the target in finite time. It also provides algorithms and regulation rules governing the runs that reach the targets while obeying state constraints.  相似文献   
36.
The most common type of bacterial meningitis in the developed countries is caused by Neisseria meningitidis bacteria, which cause meningococcal meningitis. Case fatality rate can be between 3% and 10% in developed countries and as high as 20% in African countries. During epidemics in sub-Saharan countries, the so-called meningitis belt, the case fatality rate can peak to 70% or higher. Some people who have bacterial meningitis experience some form of after effects: epilepsy, damaged eyesight, hearing loss, brain damage. There is no immunity after infection. Approximately on average 10% of the population at any time carry the germs for days, weeks, or months. Carriers can infect other individuals by close contacts, even though they do not become ill themselves. An age-structured mathematical model is formulated that enables the understanding of the dynamics of the infection transmission. The model is used to study the conditions for the stability of the disease-free steady state (which imply extinction of the disease) and the existence of an endemic state (which leads to persistence of the disease in the population). The results of the model are applied to identify the contribution of the carriers to the transmission of the disease. Final epidemiological conclusions are given.  相似文献   
37.
After describing simplified equations exspressing the temparature dependency of the viscosity of carrier gases (helium, nitrogen and hydrogen ) relative to a base value, absolute relationships based on the kinetic theory of gases are discussed. Comparative data obtained using various calculation methods are given and are compared to measured values. Based on the kinetic relationshipsm, of viscosity. Finally, the influence of pressure on the viscosity is also briefly discussed. As a supplement, Viscosity data are tabulated for the three gases in the range of 0°C to 400°C in increments of 2 K, calculated using the kinetic relationships.  相似文献   
38.
We report on capillary isoelectric focusing-mass spectrometry (CIEF-MS) of complex peptide mixtures in the absence of carrier ampholytes. Furthermore, the use of low concentrations of carrier ampholytes as mere spacers is investigated. Carrier ampholytes are complex mixtures of amphoteric compounds with high buffering capacity. Since all peptides are amphoteric compounds by themselves, the use of carrier ampholytes may be superfluous to establish a stable pH gradient in CIEF analysis of protein digests. Our research showed that when carrier ampholytes are omitted, the analyte ions are not focused at their isoelectric point. The analytes are charged, leading to electrophoretic mobility uncharacteristic for CIEF. The method was tested for a five-protein-mixture at 0.02 mg/mL per protein and 0.05 mg/mL per protein. At the lower concentration, the analytes were stacked during the focusing process in only a limited length of the capillary. Therefore, the higher concentration led to better separation efficiency. It was found that at low concentration (0.20%) the carrier ampholytes could work as spacers. Though it led to sensitivity losses of 15-45%, this was compensated by the higher separation efficiencies seen. The method was evaluated with an eight-protein-mixture, of which all could be identified after performing MS/MS.  相似文献   
39.
40.
综述了国内外在天然高分子药物微球载体材料研究及应用中的进展状况,主要从天然高分子药物微球载体材料的分类、微球的制备方法及特点、载药微球的给药途径和应用等进行概括,并对目前所存在的问题进行了描述。  相似文献   
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